Based on the team’s analysis, the lime clasts in their samples are not consistent with this method. Rather, Roman concrete was probably made by mixing the quicklime directly with the pozzolana and water at extremely high temperatures, by itself or in addition to slaked lime, a process the team calls “hot mixing” that results in the lime clasts.
“The benefits of hot mixing are twofold,” Masic said.
“First, when the overall concrete is heated to high temperatures, it allows chemistries that are not possible if you only used slaked lime, producing high-temperature-associated compounds that would not otherwise form. Second, this increased temperature significantly reduces curing and setting times since all the reactions are accelerated, allowing for much faster construction.”
And it has another benefit: The lime clasts give the concrete remarkable self-healing abilities.
When cracks form in the concrete, they preferentially travel to the lime clasts, which have a higher surface area than other particles in the matrix. When water gets into the crack, it reacts with the lime to form a solution rich in calcium that dries and hardens as calcium carbonate, gluing the crack back together and preventing it from spreading further.
Oh that’s cool. Why on this !c though?